Chloro-Bridged Dimeric Cadmium(II)-Isothiocyanate Complex with a Tridentate NNN Type Ligand: Synthesis, X-ray Structure, Thermal Analysis

Hopa C., Alkan M., Kazak C., Arslan N. B., Kurtaran R.

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, vol.40, no.2, pp.160-164, 2010 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 40 Issue: 2
  • Publication Date: 2010
  • Doi Number: 10.1007/s10870-009-9625-x
  • Journal Name: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.160-164
  • Keywords: Chloro-bridged, Hydrogen bond, Thiocyanate, Dimeric Cd(II) complex, CRYSTAL-STRUCTURE, CADMIUM(II), POLYMERS
  • Akdeniz University Affiliated: No

Abstract

The dinuclear cadmium(II) complex with 2,6-bis(3,4,5-trimethyl-N-pyrazolyl)pyridine (btmpp) has been synthesized, and characterized by single crystal X-ray diffraction, IR, UV-Vis and TGA-DTA methods. Cd atoms are located in a distorted octahedral environment in the complex. The complex crystalizes in monoclinic space group C 2/c, with unit cell dimensions a = 20.5636(12) a"<<, b = 14.0167(13) a"<<, c = 15.6598(11) a"<<, beta = 113.425(5)o, V = 4141.7(5) a"<<(3). There are two intermolecular and a intramolecular hydrogen bonds interactions in crystal.