Synthesis of chalcone-containing zinc and cobalt metallophthalocyanines; investigation of their photochemical, DPPH radical scavenging and metal chelating characters

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Baran A., Karakilic E., FAİZ Ö., Ozen F.

ORGANIC COMMUNICATIONS, vol.13, no.2, pp.65-78, 2020 (ESCI)

  • Publication Type: Article / Article
  • Volume: 13 Issue: 2
  • Publication Date: 2020
  • Doi Number: 10.25135/acg.oc.80.20.05.1639
  • Journal Name: ORGANIC COMMUNICATIONS
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus, Academic Search Premier, Directory of Open Access Journals, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.65-78
  • Keywords: Phthalocyanines, photochemical studies, singlet oxygen, quantum yields, metal chelating, DPPH radical scavenging, SUBSTITUTED PHTHALOCYANINES, ANTIOXIDANT ACTIVITY, AZAPHTHALOCYANINES, PHOTOSENSITIZERS, DERIVATIVES, ABSORPTION, REDUCTION, WATER
  • Open Archive Collection: AVESIS Open Access Collection
  • Akdeniz University Affiliated: Yes

Abstract

In this study, two new phthalocyanines (M = Zn and Co) were synthesized using the (E)-4-(4-(3-(4-(benzyloxy)phenyl)acryloyl)phenoxy)phthalonitrile (3) as ligand prepared from the chemical reaction of 4-nitrophthalonitrile with (E)-3-(4-(benzyloxy)phenyl)-1-(4-hydroxyphenyl)prop-2-en-l-one (2). All compounds were characterized using by H-1-NMR, C-13-NMR, UV-Vis, FT-IR, and MALDI-TOF mass spectra. Singlet oxygen quantum yields of the synthesized compounds, aggregates in different solutions, metal chelating and 2,2-Diphenyl-1-picrylhydrazyl (DPPH) radical scavenging properties were reported.