Synthesis, crystal structure and biological activity of the nickel(II) complex of 2,6-diacetylpyridinedihydrazone


Azaz A. D., Celen S., Namli H., Turhan O., Kurtaran R., Kazak C., ...More

TRANSITION METAL CHEMISTRY, vol.32, no.7, pp.884-888, 2007 (SCI-Expanded, Scopus)

  • Publication Type: Article / Article
  • Volume: 32 Issue: 7
  • Publication Date: 2007
  • Doi Number: 10.1007/s11243-007-0242-2
  • Journal Name: TRANSITION METAL CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.884-888
  • Akdeniz University Affiliated: No

Abstract

A complex of Ni-II with 2,6-diacetylpyridinedihydrazone (L) towards nickel(II) has been prepared and characterized by means of elemental analyses, IR, electronic spectra and single crystal X-ray analyses. [NiL2](NO3) was crystallized in the tetragonal space group P-4 21 c. The complex exhibits the expected coordination sphere with six nitrogen atoms coordinated to the central Ni-II with a deformation from pseudo-octahedral geometry. Antimicrobial activities of the ligand and its complex were investigated.