The removal of Pb2+, Cu2+ and Fe3+ from aqueous solution by a new adsorbent synthesized from Ti(OPrn)4 by sol-gel process


ERDEMOĞLU S., Sayilkan F., Akarsu M., Şener Ş., Sayilkan H.

Fresenius Environmental Bulletin, vol.12, no.1, pp.51-55, 2003 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 12 Issue: 1
  • Publication Date: 2003
  • Journal Name: Fresenius Environmental Bulletin
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.51-55
  • Keywords: Adsorbent, Adsorption, Cu, Fe, Pb, Sol-gel process
  • Akdeniz University Affiliated: No

Abstract

Removal of Cu(II), Pb(II) and Fe(III) ions from aqueous solutions was studied by using a new adsorbent synthesised by hydrolysis and subsequent condensation of Ti(OPrn)4 by sol-gel process. Metal ion adsorption was highly increased when the adsorbent surface was covered with a coating solution of hydrolysed NH2- and SH-functional silanes prepared in methanol. Adsorption conditions for Cu, Pb and Fe ions were optimized. It was concluded that Cu was retained to 100% on SH-functional silane coated adsorbents, whereas Fe(III) and Pb(II), 89% and 100%, resp., on NH2-functional silane coated adsorbents.