Effects of structural isomerism on solution behaviour of solutes: Apparent molar volumes and isentropic compression of catechol, resorcinal, and hydroquinone in aqueous solution at T = (283.15, 293.15, 298.15, 303.15, and 313.15) K

BAYRAM E., Ayranci E.

JOURNAL OF CHEMICAL THERMODYNAMICS, cilt.42, sa.9, ss.1168-1172, 2010 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 9
  • Basım Tarihi: 2010
  • Doi Numarası: 10.1016/j.jct.2010.04.018
  • Dergi Adı: JOURNAL OF CHEMICAL THERMODYNAMICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1168-1172
  • Anahtar Kelimeler: Volumetric properties, Structural isomerism, Dihydroxybenzene, Hydrophobic hydration, ORGANIC SOLUTES, COMPRESSIBILITIES, TEMPERATURE, ANTIOXIDANT
  • Akdeniz Üniversitesi Adresli: Evet

Özet

Effects of structural isomerism on solution behaviour of dihydroxybenzenes were examined through the determination of volumetric properties such as apparent molar volumes, apparent molar isentropic compressions, and isobaric expansions. The isomers were 1,2-dihydroxybenzene (catechol), 1,3-dihydroxybenzene (resorcinol). and 1,4-dihydroxybenzene (hydroquinone). The volumetric properties were determined from accurate density and speed of sound measurements at T = (283.15, 293.15, 298.15, 303.15, and 313.15) K and at various concentrations. Values at infinite dilution of these parameters were obtained by suitable extrapolation procedures. The results are discussed in terms of hydrophobic, hydrogen bonding, and dipole-dipole interactions between the three isomers and water. Catechol was found to have the strongest hydrophilic and the weakest hydrophobic interactions with water among the three isomers. (C) 2010 Elsevier Ltd. All rights reserved.