Mechanical, anti-bacterial, and easy-to-clean properties of hybrid polymer-based composites containing modified SiO2 prepared by thermal polymerization

KESMEZ Ö., ARPAÇ E., KİRAZ N., Selli N. T., TUNALİ A.

CHEMICAL PAPERS, cilt.74, sa.10, ss.3383-3398, 2020 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 74 Sayı: 10
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1007/s11696-020-01167-5
  • Dergi Adı: CHEMICAL PAPERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core
  • Sayfa Sayıları: ss.3383-3398
  • Anahtar Kelimeler: Polymer composites, Cross-linking, Radical polymerization, Thermal properties, Hybrid, SiO2, CROSS-LINKED POLYMERS, PRIMARY CYCLIZATION, PMMA, NANOCOMPOSITES, DEGRADATION, KINETICS, COATINGS, ALUMINA, HETEROGENEITY, POLYESTERS
  • Akdeniz Üniversitesi Adresli: Evet

Özet

The advance in modern technology brings about the needs arising in the field of materials. In this study, thermal behavior, mechanical properties, composite morphology, anti-bacterial efficiency, and easy-to-clean properties of the hybrid composite polymers consisting of 2-hydroxyethyl methacrylate-diurethane dimethacrylate (HEMA-DUDMA) as an organic polymer and 3-(trimethoxysilyl)propyl methacrylate-modified SiO2 used as a reinforcement were investigated. Organic polymers were prepared by free radical polymerization via thermal methods. For this purpose, HEMA was used as the monofunctional methacrylate and ethylene glycol dimethacrylate; triethylene glycol dimethacrylate and DUDMA were used as the difunctional methacrylate compounds. The modified SiO2 ceramic particles were added into the optimum organic polymer, and it was provided anti-bacterial and easy-to-clean properties for the obtained hybrid polymer composites. The conclusion reached a high hardness value, thermally stable, anti-bacterial, and easy-to-clean properties. It may be suggested that the obtained hybrid polymer composites are suitable for the potential commercial area application.